A process for reducing the odor emission of aqueous vinylaromatic/1,3-diene
copolymer dispersions and of redispersion powders obtainable therefrom by
drying, is by emulsion polymerization of a mixture containing at least one
vinylaromatic and at least one 1,3-diene in the presence of one or more
surfactant substances and optionally drying of the polymer dispersion
obtained thereby. There are 0.01% to 15.0% by weight of one or more
monomers of the branched or straight-chain alkyl esters having 1 to 8 C
atoms in the alkyl radical of monounsaturated monocarboxylic or
dicarboxylic acids and 0.01% to 15.0% by weight of one or more monomers
based upon the vinyl esters of branched or straight-chain aliphatic
carboxylic acids having 1 to 10 C atoms which are added in one step or in
two successive steps toward the end of the polymerization, when the total
content of free monomers in the aqueous copolymer dispersion is in the
range from .gtoreq.0 to .ltoreq.20% by weight. It is also possible
optionally to add the vinyl ester fraction as early as the beginning of or
during the polymerization. The data in % by weight is based in each case
on the polymer content of the dispersion.