Volatile organic compounds are removed from contaminated soil by
introducing one or both of a water soluble peroxygen compound, such as a
persulfate, and a permanganate into the soil, either in situ or ex situ,
in amounts and under conditions wherein both the soil oxidant demand is
satisfied and volatile organic compounds in the soil are oxidized. In a
preferred embodiment, when both are used, the peroxygen satisfies the soil
oxidant demand and the permanganate oxidizes the volatile organic
compounds. Sodium persulfate is the preferred persulfate and potassium
permanganate is preferred permanganate. The persulfate and the
permanganate may be added to the soil sequentially, or may be mixed
together and added as an aqueous solution.