A non-aqueous electrolyte lithium secondary battery that includes: a carbon capable of intercalating and de-intercalating lithium ion as an anode; a lithium containing material that can reversibly intercalate and de-intercalate lithium ion as a cathode; and a non-aqueous electrolyte including trans-4,5, dialkyl-1,3- dioxolane-2-one substantially free of cis-4,5-dialkyl-1,3-dioxolane-2-one and a lithium salt.

 
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