Polyurethane elastomer fibers with superior mechanical and heat distortion
properties are obtained by a method in which
(a) a segmented polyurethane polymer is produced on the basis of a
macro-diol, an aliphatic diisocyanate, and a chain extender with at least
two hydroxy and/or amino groups, where the polymer has a molar excess of
isocyanate groups over the hydroxy and/or amino groups from the macro-diol
and chain extender;
(b) the polyurethane polymer is melt-extruded to form a fiber; and
(c) The extruded fiber is subjected to a post-treatment.
Steps (a) and (b) are carried out under temperature conditions and within a
time interval where essentially no allophanate will be formed, while step
(c) is performed under temperature conditions and within a time interval
in which the polyurethane polymer is cross-linked through the formation of
allophanate.