An auto-oxidation and internal heating type reforming method and apparatus
for hydrogen production are disclosed for use in a process in which a
gaseous mixture of a hydrocarbon or an aliphatic alcohol with water vapor
is fed into contact with a mass of a reforming catalyst to bring about a
reforming reaction of the gaseous mixture to produce hydrogen, wherein a
small amount of an oxidizing catalyst is admixed with the reforming
catalyst in that mass; and a small amount of oxygen is admixed with the
gaseous mixture, whereby a portion of the hydrocarbon or aliphatic alcohol
is exothermally oxidized to generate a quantity of heat required to reform
the gaseous mixture of the hydrocarbon or aliphatic alcohol with water
vapor.