The present invention relates to a polymerizable composition, comprising a)
at least one compound of formula (I)
(RG)--A--(Stab) (I),
wherein
(Stab) is a light stabilizer radical selected from the group consisting of
sterically hindered amines, hydroxyphenyl-s-triazines,
hydroxyphenyl-benzotriazols and o-hydroxy-benzophenones; A is a spacer
group or a direct bond; and
(RG) is a group containing at least one ethylenically unsaturated
functional group; and either b1) a compound of formula (II)
Y--X (II),
wherein
X represents a group having at least one carbon atom and is such that the
free radical derived from X is capable of initiating polymerization and
Y represents a group being such that the free radical Y.multidot. derived
from it forms a stable free radical; or b2) a stable free radical
Y.multidot. and a free radical source from which a radical is formed
capable of initiating polymerization, or b3) a compound of formula (III)
##STR1##
and a catalytically effective amount of an oxidizable transition metal
complex catalyst, wherein
p represents a number greater than zero and defines the number of initiator
fragments;
q represents a number greater than zero;
[In] represents a radically transferable atom or group capable of
initiating polymerization and -[Hal] represents a leaving group; and
optionally c) one or more ethylenically unsaturated monomers or oligomers
different from those of formula (I). Further subjects of the invention are
a polymerization process, the polymers, copolymers oligomers and
cooligomers obtainable by this process and the use of the polymers,
copolymers oligomers and cooligomers as heat or light stabilizers.