A stopper for use in a substantially cylindrical bottle opening having a substantially cylindrical shape to seal the bottle opening and including a first polymer portion and a second polymer portion, wherein the second polymer portion coaxially overlies the first polymer portion. In another embodiment, the stopper includes a third polymer portion wherein the first polymer portion coaxially overlies the third polymer portion. A method of protecting liquid in a bottle with a substantially cylindrical bottle opening including providing a stopper having a substantially cylindrical shape to seal the bottle opening and closing off the bottle by insertion of the stopper into the bottle opening. A method of producing a stopper for use in a substantially cylindrical bottle opening comprising extruding a first polymer portion through an extrusion die, coaxially coating the first polymer portion with a second polymer portion to form a body.