Supported metallocene catalyst system for olefin polymerization, method for making and using the same

   
   

The present invention relates to a supported catalyst system for olefin polymerization which comprises at least one metallocene component and a support of an inorganic oxide of silica, aluminum or a polymer containing hydroxyl groups. The support is modified with an organogermane and/or organotin compound. The inventive catalyst system produces minimal reactor fouling, has excellent productivity and good hydrogen responsiveness. The present invention also relates to a process for preparing the catalyst system and to the slurry/suspension or gas-phase polymerization of olefins using the catalytic system, optionally with a small amount of aluminoxane cocatalyst.

 
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< Aluminum-oxy compound, catalyst component for polymerizing olefin, and method for producing polyolefin

< Olefin isomerization process

> Process for the catalytic oxidation of hydrocarbons

> Olefin polymerization process with alkyl-substituted metallocenes

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