Production of two alkali metal salts by a combined ion exchange and crystallization process

   
   

The invention relates a process for producing an alkali metal nitrate and an alkali metal phosphate in the same process from a phosphate raw material and a nitrate raw material comprising the steps of:

    • a) reacting the phosphate raw material with the nitrate raw material to provide an aqueous nitrophosphate feed, optionally followed by the separation of solid material,
    • b) introducing the aqueous nitrophosphate feed into a first ion exchange step comprising an alkali metal-loaded cationic exchange resin for exchanging cations present in the feed with alkali metal ions present on the resin to obtain a stream enriched in alkali metal ions,
    • c) subjecting the stream from step (b) to a first crystallization under such conditions that an alkali metal nitrate is crystallized and separating the crystallized alkali metal nitrate from the mother liquor,
    • d) introducing the mother liquor from step (c) into a second ion exchange step comprising an alkali metal-loaded cationic exchange resin for exchanging cations present in the mother liquor with alkali metal ions present on the resin to obtain a phosphate containing stream enriched in alkali metal ions, and
    • e) subjecting the stream from step (d) to a second crystallization under such conditions that an alkali metal phoshate is crystallized and separating the crystallized alkali metal phosphate from the mother liquor.
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