A method is disclosed for converting light alkanes (e.g. methane or natural gas)
to synthesis gas employing a stabilized Ni-based catalyst that is active for catalyzing
the net partial oxidation of the hydrocarbon, in the presence of O2
to CO and H2. Certain preferred catalysts comprise Ni alloyed with a
Ni-stabilizing amount of gold or silver, and a lanthanide element, carried on a
refractory support.