A multi-layered gate electrode stack structure of a field effect transistor device
is formed on a silicon nano crystal seed layer on the gate dielectric. The small
grain size of the silicon nano crystal layer allows for deposition of a uniform
and continuous layer of poly-SiGe with a [Ge] of up to at least 70% using in situ
rapid thermal chemical vapor deposition (RTCVD). An in-situ purge of the deposition
chamber in a oxygen ambient at rapidly reduced temperatures results in a thin SiO2
or SixGeyOz interfacial layer of 3 to 4A thick.
The thin SiO2 or SixGeyOz interfacial
layer is sufficiently thin and discontinuous to offer little resistance to gate
current flow yet has sufficient [O] to effectively block upward Ge diffusion during
heat treatment to thereby allow silicidation of the subsequently deposited layer
of cobalt. The gate electrode stack structure is used for both nFETs and pFETs.