The present invention provides an anti-solvent laminate body baying an excellent anti-solvent characteristic when used in a solvent atmosphere or a manufacturing method thereof. In the anti-solvent laminate body used in a solvent atmosphere comprising a substrate portion or a manufacturing method thereof an which an electrostatic latent image developing toner is printed and a printing portion formed of the electrostatic latent image developing toner, wherein the electro latent image developing toner contains a binder resin which has a solubility parameter (SP2) which is different from a solubility parameter (SP1) of a solvent which forms a solvent atmosphere by not lees than about 5(MJ/m³)^1/2 in an absolute value.