The present invention provides a protective layer thermal transfer sheet in which: a protective layer having a thermal transferring property is placed on at least one portion of one of the faces of a substrate sheet and the protective layer is formed by successively laminating at least a peeling layer, a plasticizer resistant layer and a heat adhesive resin layer on the substrate sheet, and in this structure, the heat adhesive resin layer is made from a polyester-urethane resin; and a printed article with the protective layer transferred thereto.