An energy converter reacts hydrocarbons and air on a catalyst configuration to produce a population inversion. A photovoltaic system may extract the radiating energy, and a laser system may extract a significant fraction of the reaction energy in the form of coherent radiation. The flooding of the catalyst adsorption sites with fuel and the choice of catalyst predisposes the adsorbing oxygen molecules to create mono-atomic oxygen hot-atoms, which deposit the considerable energy of oxygen adsorption directly into a reaction channel of adjacent, adsorbed and simple fuel radicals, thereby producing simple, energetic product molecules, concentrating the energy in one or a few modes, and strongly favoring inverted populations. A solid state method to stimulate precursor chemisorbed specie dissociation accelerates the reaction rates, providing a method to greatly intensify pulsed power output, increase efficiency, and to facilitate nano-scale and micro-scale thermal energy heat rejection processes.