Sidewalls of a pneumatic tire have greater resistance to failure due to
dynamic flexing and abrasion, and the tire's tread has better resistance to tearing
than with conventionally used rubber compositions, when sidewalls and tread are
formed from a compound having a major proportion by weight of synthetic rubber
(SR) and a minor proportion by weight of natural rubber (NR), and a major proportion
by weight of the SR itself consists essentially of a high cis-1,4-polybutadiene
having defined molecular architecture. The high cis-1,4-PBD has more than 90 percent
cis-structure, a poly-dispersity in the range from about 3 to 5, a number average
molecular weight Mn in the range from 100,000 to 150,000 and a degree of branching
in the range from 2 to 3.5. The sidewall compound has characteristics quite different
from one made with a typical commercially available high cis-1,4-PBD; and the tread
has excellent tear strength. The dendritic structure of the high HI cis-1,4-PBD
molecules has an unexpectedly beneficial effect on the performance characteristics
of the sidewall and tread, particularly important in a high-performance automobile tire.