A process is disclosed for purifying an aqueous feed stream comprising a product
organic acid, such as lactic acid, and a strong contaminant, such as pyruvic acid
or oxalic acid. The molar concentration of the product organic acid in the feed
stream typically is at least 20 times greater than the molar concentration of the
strong contaminant. The aqueous feed stream is contacted with a first immiscible
basic extractant that has at least a 3-fold greater affinity for the strong contaminant
than for the product organic acid. The majority of the strong contaminant and some
product organic acid become complexed with the first immiscible basic extractant.
The complexed first immiscible basic extractant is separated from the aqueous stream,
thereby producing a first effluent stream that comprises product organic acid and
that has a greater ratio of molar product organic acid to molar strong contaminant
than the aqueous feed stream did. The complexed first immiscible basic extractant
is contacted with a displacing acid. The first immiscible basic extractant has
a greater affinity for the displacing acid than it does for the strong contaminant
or the product organic acid, and as a result, product organic acid and strong contaminant
are displaced over a period of time from the complexed first immiscible basic extractant,
producing a second effluent stream that comprises a major amount of product organic
acid and a third effluent stream that comprises a major amount of strong contaminant.