The use of transalkylation catalysts to react heavy aromatic compounds of carbon
number nine (and heavier carbon numbers) with benzene to form carbon number eight
aromatics is disclosed. The catalyst system preserves ethyl-group species on the
heavier aromatics that are otherwise de-ethylated over most gas-phase transalkylation
catalysts to form undesired ethane gas with benzene or toluene. The catalyst system
also promotes methyl-group species transalkylation at selected conditions. Thus,
by using the transalkylation system, a greater yield of para-xylene or other carbon
number eight aromatics may be achieved overall within an integrated aromatics complex.