A solenoid valve includes a main valve having a valve member which switches over flow paths by contacting with and separating from valve seats in a valve casing, a solenoid operating portion to drive the valve member, and a manually-operated device including an operation rod air-tightly and slidably accommodated in a rod-insertion hole provided in the valve casing and abuts against an end surface of a movable iron core to push the movable iron core in its axial direction, and an operating member movably mounted to a mounting surface of the valve casing to drive the operation rod.