A process for preparing chlorine by catalytic gas-phase oxidation of hydrogen
chloride
over a fixed catalyst bed is disclosed that includes: making available a feed gas
stream I with hydrogen chloride and an oxygen-containing feed gas stream II, feeding
the feed gas stream I, the feed gas stream II, and, if desired, a recycled stream
Ia with hydrogen chloride, an oxygen-containing recycle stream IIa, and a recycled
stream III into an oxidation zone and oxidizing hydrogen chloride to chlorine in
the presence of a catalyst present in a fixed bed to give product gas stream IV
having chlorine, unreacted oxygen, unreacted hydrogen chloride and water vapor,
and taking the recycled stream III from the product gas stream IV, without further
treatment, and recirculating it to the oxidation zone, leaving a product gas stream IVa.