A low-cost solid polymer electrolyte fuel cell unit including a metal separator
is provided. The cell unit has a structure that may have high corrosion resistance
and durability. The solid polymer electrolyte fuel cell unit includes a polymer
electrolyte membrane, a pair of gas-diffusible electrodes fixed at opposing surfaces
of the polymer electrolyte membrane, a pair of gas-diffusible porous conductive
graphite collectors fixed in contact with the outer sides of the electrodes; a
pair of aluminum separators for introducing a fuel gas and an oxygen-containing
gas to the electrodes separately from one another, and porous conductive buffer
layers provided between the separator and the graphite collector, and having flexibility
and air permeability. The separator surfaces in contact with the buffer layers
are each provided with a conductive coating having a thickness in the range from
0.01 m to 20 m.