A process is disclosed for producing -methylstyrene, acetone, and phenol
wherein the amount of -methylstyrene produced may be controlled by selectively
converting a portion of the cumene hydroperoxide to dimethyl phenyl carbinol, the
hydrated form of -methylstyrene. The dimethyl phenyl carbinol thus produced
will lead to increased production of -methylstyrene upon dehydration in
the acid cleavage unit of the phenol plant. By controlling the fraction of the
cumene hydroperoxide reduced to dimethyl phenyl carbinol, the amount of -methylstyrene
produced in the plant can be continuously set to meet the demand of the market
for -methylstyrene. Also disclosed is a non-acidic catalyst for reduction
of cumene hydroperoxide.