A sulfonated aromatic polymer comprising the repeating structural unit of the
formula I
—O—Ar1(SO3R)n—C(CF3)2—Ar1(SO3R)n—O—Ar2—(X—Ar2)m—,
(I)
in which Ar1 and Ar2 are, independently of one another,
divalent aromatic or heteroaromatic radicals which are optionally substituted by
one or more monovalent organic groups which are inert under the conditions of use,
R is hydrogen, an alkali metal or alkaline earth metal ion or an ammonium ion,
n is an integer from 0 to 3, m is 0, 1 or 2 and X is a —CO—, —O—,
—CpH2p—, —CpF2p—
or —S— group, in which p is an integer from 1 to 10, is described.
Membranes with high proton conductivities can be produced from this polymer
and are preferably used in fuel cells.