The present invention provides a method for preparing homo- and co-polymers by
polymerizing cyclic olefin compounds using addition polymerization. The method
can produce a cyclic olefin polymer having a high molecular weight with a high
yield in the presence of, as an addition polymerization catalyst, a complex prepared
by mixing a nickel salt compound and an organoaluminoxane compound with at least
one fluorine-containing aromatic hydrocarbon compound represented by the following
formula 1 or 2 as a catalyst activator:
C6RmH6-mFormula 1
- where R is CF3; and m is from 1 to 3, or
C6FnH6-nFormula 2
- where n is from 1 to 6.