A liquid-crystalline polyester production method with a shortened reaction time
and improved productivity per unit time by using an organic basic compound containing
one nitrogen atom in a molecule is achieved by a liquid-crystalline polyester production
method comprising carrying out acylation reaction and/or ester-exchange in the
presence of an organic basic compound containing one nitrogen atom in one molecule
and satisfying the following inequality (1):
0A+0.4B (1)
wherein, A and B satisfy A={(Ech+-Ec)/(Eph+-Ep)}-1
and B=(f/fp)-1;
Ec denotes the heat of formation of the organic basic compound; Ech+
denotes the heat of formation of a compound coordinated by proton; Ep denotes the
heat of formation of pyridine; and Eph+ denotes the heat of formation
of pyridine coordinated by proton to the nitrogen atom; f and fp
independently denote parameters relevant to the steric angles.