A hybrid waveguide structure having a combination of buried waveguide sections and ridge waveguide sections on the same substrate, share a common core layer. The buried waveguide sections provide the low index contrast desirable for couplers and other device components. The ridge waveguide sections provide the high index contrast needed for efficient low-loss tightly curved waveguides. The devices are fabricated starting from a low index contrast buried waveguide. Cladding material is then selectively removed by etching down from an upper surface either side of the waveguide core to a lower surface. This forms an enhanced index contrast ridge section of the waveguide. The other sections of the waveguide core remain buried and thus retain lower index contrast. Using this approach, a variety of optical devices, such as add/drop or add-after-drop multiplexers for WDM applications based on microrings or Mach-Zehnder interferometers, can be made with large feature sizes of several microns using silica-on-glass or silica-on-silicon technology, for example, and without having to use nanofabricated semiconductor structures.