An improved method of making an ethylene acrylate (AEM) elastomer or a polyacrylate
(ACM) elastomer wherein an aqueous solution of hexamethylene diamine (HMDA) is
employed as the curative agent rather than hexamethylene diamine carbamate (HMDAC).
The HMDA reacts with the curative-site monomer derived from the monoalkyl ester
of a 1,4-butene-dioic acid in the presence of water, producing (i.e., after press-curing
and any secondary heat-curing) a crosslinked elastomer with properties essentially
indistinguishable from that produced using HMDAC as the curative agent. Advantageously,
the aqueous solution of HMDA can be blended directly into the compound or it can
be deposited on an additive such as silica or carbon black prior to blending. Elastomers
produced by the improved method according to the present invention are particularly
useful in automotive applications requiring oil resistant compositions.