A locally distributed electrode is made by placing a conducting metallic oxide
layer and a counter electrode in contact with a noble metal electroplating solution
and applying a negative potential to the metallic oxide layer relative to the counter
electrode, such that the noble metal is electrodeposited from the solution preferentially
at defect sites on a surface of the metallic oxide layer. The noble metal nuclei
are selectively electrodeposited at the defect sites to form a locally distributed
electrode made up of a dot matrix of metallic islands. For reversible electrochemical
mirror (REM) devices, the presence of the noble metal renders mirror metal electrodeposition
at the defect sites reversible so that the defects become part of the dot matrix
electrode and extraneous deposition of the mirror metal on the conducting metallic
oxide is avoided. This method avoids the use of expensive photolithography, is
readily scalable to large areas, and produces electrodes that offer the optimum
compromise between high current carrying capability and high light transmission.