The subject invention relates to a technique for synthesizing rubbery non-tapered,
random, copolymers of 1,3-butadiene and isoprene. These rubbery copolymers exhibit
an excellent combination of properties for utilization in tire sidewall rubber
compounds for truck tires. By utilizing these isoprene-butadiene rubbers in tire
sidewalls, tires having improved cut growth resistance can be built without sacrificing
rolling resistance. Such rubbers can also be employed in tire tread compounds to
improve tread wear characteristics and decrease rolling resistance without sacrificing
traction characteristics. This invention more specifically discloses a process
for the synthesis of isoprene-butadiene rubber which comprises copolymerizing isoprene
monomer and 1,3-butadiene monomer in an organic solvent in the presence of a Group
III-B metal containing catalyst system that is made by the sequential steps of
(I) reacting an organometalic compound that contains a metal from Group III-B of
the Periodic System with an organoaluminum compound at a temperature which is within
the range of 50 C. to 100 C. to produce an aluminum modified Group
III-B metal containing catalyst component, and (II) mixing the aluminum modified
Group III-B metal containing catalyst component with a halogen containing compound,
wherein the catalyst system is void of compounds selected from the group consisting
of aliphatic alcohols, cycloaliphatic alcohols, aliphatic thiols, cycloaliphatic
thiols, trialkyl silanols, and triaryl silanols.