A process for producing purified propylene oxide comprising:

    • first to sixth steps below, and
    • using heat of reaction generated in the first and/or second steps as a heat source for rectification in the fifth step and/or a heat source for rectification in the sixth step:
    • first step: a step of obtaining cumene hydroperoxide trough oxidation of cumene,
    • second step: a step of obtaining propylene oxide and cumyl alcohol by reacting cumene hydroperoxide with propylene in the presence of an epoxidation catalyst,
    • third step: a step of separating into a fraction (2) containing crude propylene oxide and a fraction (3) containing crude propylene by subjecting an outlet liquid (1) of the second step to rectification,
    • fourth step: a step of obtaining a fraction (4) containing crude propylene oxide and a fraction (6) containing cumyl alcohol by subjecting the fraction (2) to rectification,
    • fifth step: a step of obtaining a fraction (7) containing purified propylene oxide by subjecting the fraction (4) to rectification, and
    • sixth step: a step of obtaining a fraction (5) containing purified propylene by subjecting the fraction (3) to rectification.
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