A process for the double bond isomerization of an olefin, which process comprises
contacting a feed comprising the olefin with an isomerization catalyst, wherein
prior to contacting the feed with the isomerization catalyst one or more components
of the feed are pretreated by contacting with a pretreating material which comprises
a zeolite which has a pore size of at least 0.35 nm; a plant which is suitable
for carrying out the isomerization process; and a process for treating an olefin
mixture which comprises a linear -olefin and a vinylidene olefin which is
isomeric to the linear -olefin and which is of the general formula CH2C(R1)R2,
wherein R1 represents an ethyl group and R2 represents a
linear 1-alkyl group, which process comprises isomerizing the vinylidene olefin
to form a double bond isomer of the vinylidene olefin by contacting a feed comprising
the olefin mixture with an isomerization catalyst, and separating the linear -olefin
from the double bond isomer of the vinylidene olefin, wherein prior to contacting
the feed with the isomerization catalyst one or more components of the feed are
pretreated by contacting with a pretreating material which comprises a zeolite
which has a pore size of at least 0.35 nm.