A black and white monosheet substantially light-insensitive thermographic recording
material comprising a support and a thermosensitive element, the thermosensitive
element containing a substantially light-insensitive organic silver salt, an organic
reducing agent therefor in thermal working relationship therewith, a binder and
at least one toning agent, wherein the at least one toning agent is selected from
compounds represented by formula (I):
##STR1##
wherein R1 is an alkyl group optionally substituted with a hydroxy,
carboxy, carboxy ester, acyl or carbonato group; X is S, O or N—R6;
R6 is an optionally substituted alkyl group; R2, R3,
R4 and R5 independently represent a hydrogen atom, a halogen
atom or an alkyl, an alkoxy, a thio-alkoxy, a nitro, a cyano, a carboxy, a carboxy
ester, an acyl, an aldehyde, an acylamido, a sulphonamido, an acylamino, a carbonato,
a hydroxy or an aryl group or at least one of R2 and R3,
R3 and R4 and R4 and R5 independently
represent the atoms necessary to form a carbocyclic or heterocyclic group or at
least one of R1 and R5 and R2 and R6 independently
represent the atoms necessary to form a heterocyclic ring; and compounds represented
by formula (II):
##STR2##
wherein R7 is an optionally substituted alkyl group; Y is S, O
or N—R10; R10 is an optionally substituted alkyl group;
R8 and R9 independently represent a hydrogen atom, a halogen
atom or an alkyl, an alkoxy, a thio-alkoxy, a nitro, a cyano, a carboxy, a carboxy
ester, an acyl, an aldehyde, an acylamido, a sulphonamido, an acylamino, a carbonato,
a hydroxy or an aryl group or R8 and R9 represent the atoms
necessary to form a heterocyclic or a non-aromatic carbocyclic ring or at least
one of R8 and R10 and R9 and R7 independently
represent the atoms necessary to form a heterocyclic ring; and both R8 and
R9 cannot both be an alkyl group.