A sensor comprises: a pump cell comprising an inner pump electrode, an outer
pump
electrode, a pump cell electrolyte layer interposed between the inner pump electrode
and the outer pump electrode and a cell isolation layer disposed on the inner pump
electrode on a side opposite the pump cell electrolyte, wherein the outer electrode
is in fluid communication with a reducing gas. A reference cell is in operable
communication with the pump cell, the reference cell comprising an outer reference
electrode and an inner reference electrode, and a reference cell electrolyte interposed
between the outer reference electrode and the inner reference electrode. A diffusion
limiting material flanks both sides of a chamber formed between the cell isolation
layer and a cell separation layer, wherein the cell separation layer comprises
a via coaxial and in fluid communication with the inner pump electrode, the diffusing
limiting material, and the outer reference electrode, and wherein the diffusion
limiting material has a gas permeability such that the limiting current of oxygen
in air is about 0.05 mA to about 5 mA per cm2 of pump electrode area.