This invention relates to a process for the manufacture of aromatic carboxylic
acids by exothermic liquid phase oxidation of an aromatic feedstock. More particularly,
this invention relates to the efficient energy recovery of the exotherm produced
by the liquid phase oxidation of an aromatic feedstock. An apparatus useful in
recovery of energy from the preparation of aromatic carboxylic acids by the exothermic
liquid phase reaction of an aromatic feedstock is described where the primary means
of energy recovery is by raising moderate pressure steam. This is coupled with
a process to recovery low temperature energy using a process commonly known as
an organic Rankine cycle and/or a heat pump. The combination of energy recovery
methods increases the overall energy recovery and enables the recovery of reaction
energy as either thermal energy (steam) or work or a combination of both.