The present invention provides a method for manufacturing a zeolite
comprising following steps of: (1): calcining crystals obtained by
hydrothermal synthesis reaction of a silicon compound; (2): contact
treating a calcined product obtained by the step (1) with an aqueous
solution including an amine and/or a quaternary ammonium compound; (3):
calcining a treated product obtained by the step (2); and (4): contact
treating the calcined product obtained by the step (3) with an aqueous
solution including ammonia and/or an ammonium salt.According to the
present invention, a method is also provided wherein
.epsilon.-caprolactam is manufactured by Beckmann rearrangement reaction
of cyclohexanone oxime in a gaseous phase in the presence of the zeolite
manufactured by the above-described method.