Water soluble associative polymers and compositions comprising them
together with alkali metal salts of carboxylic acid are disclosed.
Methods comprise introducing into a wellbore a fluid comprising such
associative polymers and alkali metal salts of carboxylic acid, e.g.,
cesium formate. Disclosed water soluble associative polymers have
functionality including at least sulfonate groups, carboxylate groups and
hydrophobes associative with one another in a saturated aqueous solution
of an alkali metal salt of a carboxylic acid. Water soluble associative
polymers are formed as the polymerization reaction product of reactants
comprising an AMPS reactant, an alpha, beta-unsaturated carbonyl reactant
and a hydrophobe reactant selected from acrylic esters, methacrylic
esters and a mixture of any of them, having a --COOR moiety wherein R is
a hydrophobe which, as hydrophobe moieties of the resultant associative
polymer, are associative with one another in a saturated aqueous solution
of an alkali metal salt of a carboxylic acid.