Method for synthesis of (2S, 3aS, 7aS)-1-{(S)-alanyl}-octahydro-1H -indole-2-carboxylic acid derivatives and use for synthesis of perindopril

Process for the industrial synthesis of the compounds of formula (I): ##STR00001## wherein R.sub.1 represents a hydrogen atom or an alkyl or benzyl group, and R.sub.2 represents a group that protects the amino function.

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> 3-Substituted piperidines comprising urea functionality, and methods of use thereof

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