An optical element, composed of an one-dimensional photonic crystal of a triangular prism shape and a multilayer film and a phase modulation unit are used together, with the phase modulation unit adjacent or abutting to a light input end surface of the optical element. Input light is phase-modulated by the phase modulation unit in the same period and direction as those of photonic crystal so that only specific high-order band light can be propagated through the optical element. When this optical element is formed in an optical waveguide, a small-size spectroscopic device having high resolving power can be provided.