A hydrocarbon fuel reformer for producing diatomic hydrogen gas is
disclosed. The reformer includes a first reaction vessel, a shift reactor
vessel annularly disposed about the first reaction vessel, including a
first shift reactor zone, and a first helical tube disposed within the
first shift reactor zone having an inlet end communicating with a water
supply source. The water supply source is preferably adapted to supply
liquid-phase water to the first helical tube at flow conditions
sufficient to ensure discharge of liquid-phase and steam-phase water from
an outlet end of the first helical tube. The reformer may further include
a first catalyst bed disposed in the first shift reactor zone, having a
low-temperature shift catalyst in contact with the first helical tube.
The catalyst bed includes a plurality of coil sections disposed in
coaxial relation to other coil sections and to the central longitudinal
axis of the reformer, each coil section extending between the first and
second ends, and each coil section being in direct fluid communication
with at least one other coil section.