A process for closing hollow-core defects, called micropipes, during
growth by CVD of a SiC crystal on a SiC single crystal substrate having
hollow-core defects, and a crystal obtained according to the process, by
contacting the SiC crystal with a source gas adjusted to a C/Si atom
ratio range in which the crystal growth rate is determined by the carbon
atom supply limitation, then epitaxially growing and laminating a
plurality of SiC crystal layers, wherein hollow-core defects in the SiC
single crystal substrate dissociate into a plurality of dislocations
given by small Burghers vector in order not to propagate to the crystal
surface. In addition, the present invention provides a fabrication
process of a SiC crystal, wherein a first SiC crystal is made as a buffer
layer, and a further SiC crystal is layered thereon using a source gas
adjusted to be higher than that of the C/Si ratio when forming the buffer
layer, whereby a desired film property is conferred.