The invention encompasses late transition metal catalyst systems
immobilized on solid supports and their use in heterogenous
polymerization processes, particularly in gas phase polymerization of
olefin monomers. Preferred embodiments include a late transition metal
catalyst system comprising a Group 9, 10, or 11 metal complex stabilized
by a bidentate ligand structure immobilized on a solid porous metal or
metalloid oxide particle support, particularly those comprising silica.
The gas phase polymerization process for olefin monomers comprises
contacting one or more olefins with these catalyst systems under gas
phase polymerization conditions.