This invention relates to the reversible protection of hydroxy-silane
functional groups by acid cleavable protecting groups. The development of
reversible protecting groups greatly enhances the current utility of
silanes while introducing further novel applications. For instance,
reversibly protected silanes are of particular value in applications
where room temperature cure and/or adhesion is of value, such as
coatings, high resolution imaging, caulks, adhesives, sealents, gaskets,
and silicones. Reversibly protected silanes can also be beneficially used
in reticulating agents, and in sizing agents, tires, and release
coatings. The incorporation of reversibly protected silanes into coating
resins is of particular value. The reversibly protected silane can be
incorporated into the coating resin by polymerizing a monomer containing
the reversibly protected silane into the resin or by post-addition into
the coating formulation. The reversibly protected silane remains
protected under basic conditions, such as in a coating formulation that
contains a volatile base, for instance ammonium hydroxide. However,
deprotection occurs under mildly acidic conditions. Thus, as a coating
formulation containing a volatile base dries the volatile base evaporates
and deprotection occurs. This allows for controlled room temperature
crosslinking to occur with hydroxy-functionalized polymers. The present
invention more specifically discloses a modified silane compound
consisting of a silane having 3 or 4 acetal moieties bonded thereto.