The present invention relates to an instrument for measuring in relatively
short periods of time concentrations of constituents in optically dense
materials using the spectra near infrared radiation transmitted through
thick samples of the material while the material is either stationary or
flowing. The invention uses a broadband incandescent intensity stabilized
light source combined with collimating optics to transmit a parallel beam
of light through the material under test. The light transmitted through
the material is then collected by a focusing lens and imaged onto a
rectangular entrance slit of a special purpose spectrometer. This
spectrometer has no moving parts and employs a fixed diffraction grating
to physically spread the image of the entrance slit into a continuous
range of wavelengths. A portion of the diffracted slit images covering
the selected portion of the near infrared range is focused onto an array
of individual rectangular photodiodes. By using relatively large area
photodiodes and a relatively small number of photodiodes, high
sensitivity is achieved and low intensity radiation levels can be
measured quickly. By using a relatively narrow spectral range, medium
resolution can be achieved. The outputs of each photodiode, or the
outputs of a selected number of the photodiodes, are fed into current to
voltage converters: either resistive (instantaneous) or preferred
capacitive (integrating). Thus the outputs of all photodiodes are
measured in parallel, which reduces the time to acquire the spectra. The
gain of these current to voltage converters is programmable so that both
high intensity and low intensity near infrared radiation levels can be
measured without reducing the intensity of the radiation incident on the
material under test and thereby eliminating the need for moving parts in
the spectrometer. After the spectra are acquired, they are operated on by
models developed to predict the percentages of various constituents in
the material. These models are pre-calibrated using spectra obtained from
materials of known concentrations and developed using chemometric, neural
net, and/or genetic algorithms.