Method and apparatus for using a silylating agent after exposure to an
oxidizing environment for repairing damage to low-k dielectric films are
described. Plasma photoresist removal, or ashing, may damage bonds in the
low-k materials, which may lead to a significant increase in the
dielectric constant of the materials. The silylating agent may be used to
repair damage to the low-k films after the ashing process. Additionally,
a curing process using an oxidizing environment may damage bonds in low-k
materials, which may subsequently be repaired by a silylating process.
The described method and apparatus may be used with low-k dielectric
films including hydrophobic porous oxide films. A chamber for processing
a wafer in an oxidizing environment and subsequently performing a
silylation process includes an oxidizing agent inlet and a silylating
agent inlet. Additionally, a chamber for performing an etch process,
processing a wafer in an oxidizing environment, and subsequently
performing a silylation process includes an oxidizing agent inlet, a
silylating agent inlet, and an etch gas inlet. A cluster tool can include
a chamber for processing a wafer in an oxidizing environment and
subsequently performing a silylation process, a wafer in/out module, and
may include additional processing modules such as etch modules,
deposition modules for depositing low-k layers, and deposition modules
for depositing cap layers.