A reaction product comprising an adduct of a mid-range vinylidene content
PIB polymer composition and maleic anhydride, a phenolic compound or a
compound having a reactive site for subsequent amination. The PIB
composition comprises a relatively low molecular weight, mid-range
vinylidene content PIB polymer product wherein at least about 90% of the
PIB molecules present in the product comprise alpha or beta position
isomers. The vinylidene (alpha) isomer content of the product may range
from 20% to 70% thereof and the content of tetra-substituted internal
double bonds is very low, preferably less than about 5% and ideally less
than about 1 2%. The mid-range vinylidene content PIB polymer products
may be prepared employing a liquid phase polymerization process conducted
in a loop reactor at a temperature of at least 60.degree. F. using a
BF.sub.3/methanol catalyst complex and a contact time of no more than 4
minutes.