The present invention provides a method for producing cyclic
chlorophosphazene oligomers, in particular the trimer and tetramer, in a
high yield and selectivity. The method for producing cyclic
chlorophosphazene oligomers involves the reaction between chlorinated
phosphorus and ammonium chloride in the presence of a reaction catalyst,
wherein 1) moisture is present in the reaction system at a molar fraction
of 5.times.10.sup.-3 or less based on the total moles of the chlorinated
phosphorus added to the reaction system, and 2) the ammonium chloride has
an average particle size of 10 .mu.m or less and the value of particle
size distribution of 2 or more, estimated by the Rosin-Rammler equation.