The specification discloses a process for the production of olefins,
including ethylene, propylene and butenes, from methane, the process
comprising first, second and third reaction steps operated in tandem. In
the first reaction step, hydrogen chloride, perchloroethylene and oxygen
are reacted in the presence of a catalyst, using methane as a diluent, to
yield hexachloroethane and water. In the second reaction step, the
hexachoroethane from the first reaction step is reacted with methane to
produce methyl chloride, hydrogen chloride and perchloroethylene. In the
third reaction step, the methyl chloride from the second reaction step is
reacted to give the desired olefins and hydrogen chloride. By recycling
the perchloroethylene from the second reaction step and the hydrogen
chloride from both the second and third reaction steps to the first
reaction step, a balanced process is achieved that is self-sufficient in
chlorine values.