A method of producing cis-1,4-polydienes, the method comprising the step
of contacting conjugated diene monomer with a lanthanide-based catalyst
system in the presence of less than 20% by weight of organic solvent
based on the total weight of monomer, organic solvent, and resulting
polymer, where the lanthanide-based catalyst system is the combination of
or reaction product of (a) a lanthanide compound, (b) an organoaluminum
hydride, (c) a trihydrocarbylaluminum, and (d) a halogen-containing
compound.