A method for the production of fatty acid esters of primary and/or
secondary alcohols from raw, unpurified oils or fats containing free
fatty acids and slimy substances or from waste oils loaded with free
fatty acids from the food industry. Acidic catalytic esterification is
performed on the free fatty acids along with extensive deactivation of
the slimy substances present with respect to the disadvantageous
emulsion-forming property thereof, whereby a water-free primary and/or
secondary alcohol and a highly acidic hygroscopic catalyst are added to
the starting substance in the form of crude oil or fat or waste oil, the
reaction product is rinsed with glycol from a prior alkaline
transesterification, whereupon alkaline transesterification occurs for
the unmodified remaining glyceridically bound fatty acids in the reaction
product of the acidic-catalytic esterification process.