A process for the disproportionation and transalkylation of toluene and
the heavy aromatics comprises: subjecting a first stream of toluene, and
a stream enriched in aromatics of nine carbon atoms to toluene
disproportionation and transalkylation reactions in the presence of
hydrogen in a first reaction zone to produce a first product mixture
comprising benzene, aromatics of eight carbon atoms and heavy aromatics
of ten and more carbon atoms; subjecting a second stream of toluene, and
a stream enriched in heavy aromatics of ten and more carbon atoms to
transalkylation reaction in the presence of hydrogen in a second reaction
zone to produce a second product mixture comprising benzene, aromatics of
eight carbon atoms and aromatics of nine carbon atoms; and isolating and
recovering benzene and aromatics of eight carbon atoms from the first and
second product mixtures.