The present invention provides compounds of Formula (I): ##STR00001## or a stereoisomer or pharmaceutically acceptable salt form thereof, wherein the variables A, R.sup.1, R.sup.2, R.sup.3, R.sup.4, Z, U, X, Y, Z.sup.a, and n are defined are as defined herein, which are useful as inhibitors of matrix metalloproteinases (MMP) and/or TNF-.alpha. converting enzyme (TACE), or a combination thereof.

 
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< Intermediate precursor compositions used to make supported catalysts having a controlled coordination structure and methods for preparing such compositions

< C13 alcohol mixture and functionalised C13 alcohol mixture

> In situ thermal processing of a relatively permeable formation while controlling pressure

> Gradient fabrication to direct transport on a surface
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